Course Information


Course Information
Course Title Code Semester L+U Hour Credits ECTS
INORGANIC CHEMISTRY II KİM0308 6. Semester 4 + 0 4.0 5.0

Prerequisites None

Language of Instruction Turkish
Course Level Bachelor's Degree
Course Type Compulsory
Mode of delivery
Course Coordinator
Instructors
Assistants
Goals To acquire systematic and comprehensive basic information about the structure, nomenclature, isomers, geometric structures and magnetic properties of coordination compounds and to develop the ability to think about Inorganic Chemistry.
Course Content Coordination compounds, ligands, nomenclature of coordination compounds, isomerism and chemical bond in coordination compounds, 18 electron rule, valance bond theory, crystal field theory, molecular orbital theory, solids, metals.
Learning Outcomes 1) He/She associates the name of the coordination compounds with the formulas of coordination compounds.
2) He/She uses classifies the types of isomers observed in coordination compounds, examines the isomers of coordination compounds given closed formulas.
3) He/She evaluates the historical development of coordination chemistry and the effects of the scientists involved in the coordination chemistry.
4) He/She explains the structures and properties of coordination compounds on the basis of different theories.
5) He/She writes reactions about the synthesis of coordination compounds, interprets the reactions related to coordination compounds.
6) He/She classifies metals based on their physical and chemical properties.
7) He/She classifies solids and crystals.
8) He/She uses the library and other sources of information to obtain information about coordination chemistry.

Weekly Topics (Content)
Week Topics Teaching and Learning Methods and Techniques Study Materials
1. Week MOLECULAR ORBITAL THEORY (MOT): Interaction of atomic orbitals, Molecular orbital energy diagrams of A2, AB, AB2, AB3 and AB4 type molecules. Lecture; Question Answer; Discussion

 Homework
2. Week COORDINATION CHEMISTRY: Basic consept of coordination chemistry, Coordination compounds, Ligands, Developments in coordination chemistry. Lecture; Question Answer; Discussion

 Homework
3. Week NOMENCLATURE OF COORDINATION COMPOUNDS. Lecture; Question Answer; Discussion

 Homework
4. Week ISOMERISM IN COORDINATION COMPOUNDS: Structural isomerism (Ligand isomerism, Ionization isomerism, Hydrate (solvent) isomerism, Coordination isomerism, Linkage isomerism, Polymerization isomerism) and Stereoisomerism (Diastereoisomerism (Geometrical (c-s-/trans-) isomerism, Conformation isomerism), Optical isomerism). Lecture; Question Answer; Discussion

 Homework
5. Week 18 ELECTRON RULE [EFFECTIVE ATOMIC NUMBER (EAN) RULE]: Werner complexes, Carbonyl complexes (metal carbonyls), Nitrosil complexes, Dinitrogen complexes, Dioxygen complexes. Lecture; Question Answer; Discussion

 Homework
6. Week 18 ELECTRON RULE [EFFECTIVE ATOMIC NUMBER (EAN) RULE]: Olefin complexes, Alkyne complexes, Arene complexes, Cyclopentadienyl complexes Lecture; Question Answer; Discussion

 Homework
7. Week VALANCE BOND THEORY: Linear complexes, Tetrahedral complexes, Square planar complexes, Octahedral complexes. Lecture; Question Answer; Discussion

 Homework
8. Week CRYSTAL FIELD THEORY (CFT): Basic concept of CFT, The orbital splitting diagrams for octahedral, tetrahedral and square planar complexes. Lecture; Question Answer; Discussion

 Homework
9. Week CRYSTAL FIELD THEORY (CFT): Calculation of crystal field stabilization energy or crystal field splitting energy (CFSE) in octahedral, tetrahedral and square planner complexes, The orbital splitting diagrams for other complexes. Lecture; Question Answer; Discussion

 Homework
10. Week CRYSTAL FIELD THEORY (CFT): Jahn-Teller effect (tetragonal distortion), 10Dq parameter and electronic spectra, Spectrochemical series, Factors affecting CFSE, Effects of crystal field splitting. Lecture; Question Answer; Discussion

 Homework
11. Week MOLECULAR ORBITAL THEORY IN COORDINATION COMPOUNDS: Octahedral complexes (σ-Bonding, п-Bonding), Tetrahedral complexes and Square planar complexes. Lecture; Question Answer; Discussion

 Homework
12. Week SOLIDS: Classifications of solids and crystals, Unit cell, clarifications of crystal structures using X-ray crystallography, Ionic solids (radii ratio r + / r-, crystal defects, stacking in solids, AX (ZnS, NaCl, CsCl) and AX2 (CaF2, TiO2, SiO2) type compounds, layered structures (CdI2, CdCl2, NiAs), structures containing polyatomic ions, other lattices. Lecture; Question Answer; Discussion

 Homework
13. Week SOLIDS: Lattice energy, Born-Haber cycle, Applications of lattice energy (determination of electron, ion and proton affinities and finding enthalpies of disproportionation and formation). Lecture; Question Answer; Discussion

 Homework
14. Week METALS: Metallic character and physical properties of metals (electrical and thermal conductivity of metals, brightness of metals, thermoionic and photoelectric phenomena in metals, crystal structure of metals, ability to be beaten and withdrawn properties in metals, metal alloying feature, Theories related to bonding in metals (free electron theory, valence bond theory, molecular orbital theory), conductors, semiconductors and insulators, super conductors. Lecture; Question Answer; Discussion

 Homework

Sources Used in This Course
Recommended Sources
Anorganik Kimya; D. F. Shriver and P. W. Atkins, üçüncü baskı, çeviri editörleri: S. Özkar, A. Gül ve Y. Gök, Bilim Yayıncılık, 1999.
Chemistry of the Elements; N.N. Greenwood and A. Earnshaw, second edition, Elsevier 1997.
ICE Manual of Construction Materials: Metals and Alloys; Wei Sha, ICE, 2010.
İnorganik Kimya 2; Cemal Kaya, Palme Yayıncılık, 2008.
İnorganik Kimya; G. L. Miessler and D. A. Tarr, ikinci baskı, çeviri editörleri: N. Karacan ve P. Gürkan, Palme Yayıncılık, 2002.
Konu ile ilgili makaleler.
Metals and Alloys; Mark Anthony Benvenito, De Gruyter, 2016.
Temel Üniversite Kimyası; E. Erdik ve Y. Sarıkaya, Gazi Kitabevi, 2004.

Relations with Education Attainment Program Course Competencies
Program RequirementsContribution LevelDK1DK2DK3DK4DK5DK6DK7DK8
PY1500000000
PY2500000000
PY3500000000
PY4500000000
PY5500000000

*DK = Course's Contrubution.
0 1 2 3 4 5
Level of contribution None Very Low Low Fair High Very High
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ECTS credits and course workload
Event Quantity Duration (Hour) Total Workload (Hour)
Course Duration (Total weeks*Hours per week) 14 3
Work Hour outside Classroom (Preparation, strengthening) 14 3
Presentation (Including Preparation Time) 1 2
Report (Including Preparation and presentation Time) 1 8
Midterm Exam 1 1.5
Time to prepare for Midterm Exam 1 24
Final Exam 1 1.5
Time to prepare for Final Exam 1 24
Total Workload
Total Workload / 30 (s)
ECTS Credit of the Course
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Course Information
  • Course Information
  • Weekly Topics (Content)
  • Sources Used in This Course
  • Relations with Education Attainment Program Course Competencies
  • ECTS credits and course workload