Week
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Topics
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Teaching and Learning Methods and Techniques
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Study Materials
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1. Week
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Introduction: Coordination compounds, ligand, Werner theory, aplication of coordination compounds (as pharmaceuticals, precious metals recovery, as a catalyst), natural coordination compounds in our lives.
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Lecture; Question Answer Brainstorming
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Homework
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2. Week
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Ligands: Classification of ligands, dentant ligands, according to donor-acceptor kinds, according to electronic structure, explanation of the chelate ligands and stability, neutral and anionic ligands and nomenclature.
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Lecture Brainstorming
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Homework
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3. Week
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Coordination polyhedron and VSEPR Theory: The most common geometry in transition metal complexes, the factors determining the structures, VSEPR theory, changes in bond angles based on various factors, hybrid orbitals of energy, find the s and p character
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Lecture Brainstorming
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Homework
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4. Week
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Nomenclature of Coordination Compounds: Nomenclature of Stock and Evens-Basset system, nomenclature of anionic coordination compounds, nomenclature of cationic coordination compounds, nomenclature of the nötral coordination compound, η-complexes, κ-complexes.
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Lecture
Project Based Learning
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Homework
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5. Week
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Isomer in Coordination Compounds: Structural isomerism (ionization isomerism, hydration isomerism coordination isomerism donor atoms isomerism, polymerization isomerism), stereoisomerism (geometrical isomerism, optical isomerism, conformational isomerism) ligand isomerism.
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Lecture Brainstorming
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Homework
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6. Week
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Valence Bond Theory: Hybrid orbitals, sp, sp2, sp3, sp3d, dsp2, sp3d2 hybridisation, hybrid orbitals, valence bond theory and carbonyl compounds, valence bond theory and privileged situations.
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Lecture Brainstorming
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Homework
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7. Week
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Crystal Field Theory: Crystal Field Theory in octahedral, tetrahedral, square planar, linear, trigonalbipyramidal complexes, pairing energy, crystal field stability and crystal field splitting energy
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Lecture Brainstorming
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Homework
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8. Week
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Crystal Field Theory: The color change of coordination compounds, color and spectrochemical series, the importance of crystal field stability energy (lattice energy, hydration enthalpy, ionic radius, reduction potentials).
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Lecture Brainstorming
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Homework
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9. Week
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Crystal Field Theory: Determination energy of octahedral position, spinel structures (normal spinel, reverse spinel), Jahn Teller theory. Electronic transition metal complexes.
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Lecture Brainstorming
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Homework
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10. Week
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Molecular Orbital Theory: molecular orbitals (bonding, antibonding and bonding orbitals), applying molecular orbital theory for the diatomic molecules, applying molecular orbital theory for the coordination compounds (tetrahedral, square planar and octahedral complexes).
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Lecture Brainstorming
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Homework
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11. Week
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Molecular Orbital Theory: molecular orbitals (bonding, antibonding and bonding orbitals), applying molecular orbital theory for the diatomic molecules, applying molecular orbital theory for the coordination compounds (tetrahedral, square planar and octahedral complexes).
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Lecture Brainstorming
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Homework
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12. Week
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Ligand Field Theory: ligand field theory, orbital overlap forming bonds of π, M-L π-bound complexes (π- donor ligands and π-acceptor ligands).
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Lecture Brainstorming
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Homework
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13. Week
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Reaction Mechanisms of Complex Compounds: Stability and inertness, energy profiles, make reactions of complex compounds, substitution reactions, substitution reactions of octahedral complexes, substitution reactions of square plane complexes, trans effect.
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Lecture Brainstorming
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Homework
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14. Week
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Organometallic chemistry: definition of organometallic compounds and organometallic compounds important applications related reaction mechanisms.
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Lecture Brainstorming
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Homework
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